Product ID:PYROIL WINDSHIELD DE-ICER DI 11.5
MSDS Date:11/20/1990
FSC:6830
NIIN:00F034206
MSDS Number: BTNDS

ASHLAND OIL INC VALVOLINE INC

2900 PALUMBO DR
LEXINGTON, KY 40509-1253
US

Emergency Phone: 800-274-5263

Info Phone: 606-264-7000

Cage: 9T904

ASHLAND INDUSTRIAL PRODUCTS INC

14000 LEXINGTON, KY 40512 US

Telephone: 859-357-7777

Cage: 9T904

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 1-10%

OSHA PEL 5000 PPM

ACGIH TLV: 9000 MG/CUM

METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 55-70%

OSHA PEL 260 MG/CUM

ACGIH TLV: 262 MG/CUM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYLENE GLYCOL, GLYCOL

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 5-10%

ACGIH TLV: C 127 MG/CUM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION. SKIN:
MODERATE IRRITATION/DERMATITIS. INHALATION: NASAL/RESPIRATORY
IRRITATION/CNS EFFECTS/DEATH. INGESTION: GI IRRITATION/DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:REDNESS, TEARING, BLURRED VISION, DEFATTING,
DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE
UNCONSCIOUSNESS, VOMITING, DIARRHEA, BLINDNESS, IRRITATION.

First Aid:SKIN: WASH AREA W/SOAP & WATER. EYES: FLUSH W/PLENTY OF
WATER. INGEST: DRINK 2 GLASSES OF WATER/INDUCE VOMITING BY GIVING
IPECAC SYRUP/BY PLACING FINGER AT BACK OF THROAT. NEVER GIVE
ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. INHALE: REMOVE TO FRESH
AIR. GIVE OXYGEN/CPR IF NECESSARY. KEEP QUIET/WARM. OBTAIN MEDICAL
ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: PRODUCT CONTAINS
ETHYLENE GLYCOL. SEE SUPP

Flash Point Method:TCC
Flash Point:69F/20.6C
Lower Limits:3.2
Extinguishing Media:WATER FOG, ALCOHOL FOAM
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN
POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard:NEVER USE WELING/CUTTING TORCH ON/NEAR
DRUM (EVEN EMPTY) PRODUCT RESIDUE CAN IGNITE. VAPORS ARE HEAVIER
THAN AIR/MAY TRAVEL TO IGNITION SOURCES.

Spill Release Procedures:SMALL: ABSORB ON VERMICULITE/OTHER ABSORBENT
MATERIAL/TRANSFER TO HOOD. LARGE: ELIMINATE IGNTION SOURCES. WEAR
PROTECTIVE CLOTHING. PREVENT FROM ENTERING WATER WAYS. PUMP/VACUM
TRANSFER PRODUCT TO CLE AN CONTAINERS. TRANSFER TO CONTAINER FOR
DISPOSAL.

Handling and Storage Precautions:CONTAINERS MAY BE HAZARDOUS WHEN
EMPTIED. CONTAINERS MAY CONTAIN PRODUCT RESIDUE, ALL HAZARD
PRECAUTIONS MUST BE OBSERVED.
Other Precautions:NOTE TO PHYSICIAN: CONTAIS METHANOL. METHANOL IS
METABOLIZED TO FORMALDEHYDE/FORMIC ACID. THESE METABOLITES MAY
CAUSE METABOLIC ACIDOSIS. USE ETHANOL AS ANTIDOTE.

Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DISCARD SHOES SATURATED W/THIS PRODUCT.
Supplemental Safety and Health
NOTE TO PHYSICIAN CON'D: ETHANOL REDUCES METABOLISM OF ETHYLENE GLYCOL
TO TOXIC METABOLITES. ETHANOL SHOULD BE ADMINISTERED IN SEVERE
POISONING SINCE THE ELIMINATED HALF-LIFE OF ETHYLENE GLYCOL IS 3 H
OURS. IF MEDICAL CARE IS DELAYED, USE 3-4, 1 OUNCE ORAL "SHOTS" OF
86-PROOF WHISKEY.

Vapor Density:>1
Spec Gravity:0.83-0.84
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:CLEAR LIQUID, HOMOG SOLN
Percent Volatiles by Volume:85-100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2

Waste Disposal Methods:SMALL: ALLOW TO EVAPORATE IN HOOD. LARGE:
DESTROY LIQUID BY INCINERATION. DISPOSE OF IN ACCORDANCE W/FEDERAL,
STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.